Wagner–Meerwein rearrangement
id:
wagner-meerwein-rearrangement-280-6497037
title:
Wagner–Meerwein rearrangement
text:
A Wagner–Meerwein rearrangement is a class of carbocation 1,2-rearrangement reactions in which a hydrogen, alkyl or aryl group migrates from one carbon to a neighboring carbon. They can be described as cationic [1,2]-sigmatropic rearrangements, proceeding suprafacially and with stereochemical retention. As such, a Wagner–Meerwein shift is a thermally allowed pericyclic process with the Woodward-Hoffmann symbol [ω0s + σ2s]. They are usually facile, and in many cases, they can take place at temper
brand slug:
wiki
category slug:
encyclopedia
description:
Organic reaction
original url:
https://en.wikipedia.org/wiki/Wagner%E2%80%93Meerwein_rearrangement
date created:
date modified:
2023-12-02T02:17:19Z
main entity:
{"identifier":"Q902347","url":"https://www.wikidata.org/entity/Q902347"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/6/63/Carbocation_rearrangement_polito_2010.svg","width":366,"height":231}
fields total:
13
integrity:
15