Transition metal phosphinimide complexes
id:
transition-metal-phosphinimide-complexes-269-9161510
title:
Transition metal phosphinimide complexes
text:
Transition metal phosphinimide complexes are metal complexes that contain phosphinimide ligands of the general formula NPR3− (R = organic substituent). Several coordination modes have been observed, including terminal and various bridging geometries. In the terminal bonding mode the M-N=P core is usually linear but some are quite bent. The preferred coordination type varies with the oxidation state and coligands on the metal and the steric and electronic properties of the R groups on phosphorus.
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Transition_metal_phosphinimide_complexes
date created:
date modified:
2022-11-09T15:36:13Z
main entity:
{"identifier":"Q96410660","url":"https://www.wikidata.org/entity/Q96410660"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/6/6d/Bonding_modes_of_phosphinimide_ligands.gif","width":287,"height":407}
fields total:
13
integrity:
14