Tolman's rule
id:
tolman-s-rule-305-1874032
title:
Tolman's rule
text:
Tolman's rule states that, in a certain chemical reaction, the steps involve exclusively intermediates of 18- and 16 electron configuration. The rule is an extension of the 18-electron rule. This rule was proposed by American chemist Chadwick A. Tolman. As stated above, Tolman's rule, even for reactions that proceed via 2e− steps, is incorrect because many reactions involve configurations of fewer than 16 e−. Many examples of homogeneous catalysis involving organometallic complexes involve shutt
brand slug:
wiki
category slug:
encyclopedia
description:
Rule describing chemical reactions
original url:
https://en.wikipedia.org/wiki/Tolman%27s_rule
date created:
date modified:
2022-10-11T15:27:39Z
main entity:
{"identifier":"Q7814437","url":"https://www.wikidata.org/entity/Q7814437"}
image:
fields total:
13
integrity:
14