Thiol-yne reaction
id:
thiol-yne-reaction-319-15146239
title:
Thiol-yne reaction
text:
The thiol-yne reaction is an organic reaction between a thiol and an alkyne. The reaction product is an alkenyl sulfide. The reaction was first reported in 1949 with thioacetic acid as reagent and rediscovered in 2009. It is used in click chemistry and in polymerization, especially with dendrimers. This addition reaction is typically facilitated by a radical initiator or UV irradiation and proceeds through a sulfanyl radical species. With monoaddition a mixture of (E/Z)-alkenes form. The mode of
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Thiol-yne_reaction
date created:
date modified:
2023-12-20T15:32:45Z
main entity:
{"identifier":"Q7784672","url":"https://www.wikidata.org/entity/Q7784672"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/4/4a/Thiol-yne-reaction.svg","width":265,"height":89}
fields total:
13
integrity:
14