Stevens rearrangement

id: stevens-rearrangement-323-15719410
title: Stevens rearrangement
text: The Stevens rearrangement in organic chemistry is an organic reaction converting quaternary ammonium salts and sulfonium salts to the corresponding amines or sulfides in presence of a strong base in a 1,2-rearrangement. The reactants can be obtained by alkylation of the corresponding amines and sulfides. The substituent R next the amine methylene bridge is an electron-withdrawing group. The original 1928 publication by Thomas S. Stevens concerned the reaction of 1-phenyl-2-(N,N-dimethylamino)eth
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category slug: encyclopedia
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original url: https://en.wikipedia.org/wiki/Stevens_rearrangement
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date modified: 2023-04-06T02:43:18Z
main entity: {"identifier":"Q906103","url":"https://www.wikidata.org/entity/Q906103"}
image: {"content_url":"https://upload.wikimedia.org/wikipedia/commons/3/3c/Stevens_rearrangement_overview.svg","width":516,"height":318}
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