Smiles rearrangement
id:
smiles-rearrangement-236-18464634
title:
Smiles rearrangement
text:
In organic chemistry, the Smiles rearrangement is an organic reaction and a rearrangement reaction named after British chemist Samuel Smiles. It is an intramolecular, nucleophilic aromatic substitution of the type: where X in the arene compound can be a sulfone, a sulfide, an ether or any substituent capable of dislodging from the arene carrying a negative charge. The terminal functional group in the chain end Y is able to act as a strong nucleophile for instance an alcohol, amine or thiol. As i
brand slug:
wiki
category slug:
encyclopedia
description:
Organic reaction
original url:
https://en.wikipedia.org/wiki/Smiles_rearrangement
date created:
date modified:
2023-01-28T23:41:45Z
main entity:
{"identifier":"Q898710","url":"https://www.wikidata.org/entity/Q898710"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/b/bf/Truce_Smiles_rearrangement.png","width":1058,"height":706}
fields total:
13
integrity:
15