Sigma-bond metathesis
id:
sigma-bond-metathesis-248-3582881
title:
Sigma-bond metathesis
text:
In organometallic chemistry, sigma-bond metathesis is a chemical reaction wherein a metal-ligand sigma bond undergoes metathesis with the sigma bond in some reagent. The reaction is illustrated by the exchange of lutetium(III) methyl complex with a hydrocarbon (R-H): This reactivity was first observed by Patricia Watson, a researcher at duPont. The reaction is mainly observed for complexes of metals with d0 configuration, e.g. complexes of Sc(III), Zr(IV), Nb(V), Ta(V), etc. f-Element complexes
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wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Sigma-bond_metathesis
date created:
date modified:
2024-04-20T23:08:20Z
main entity:
{"identifier":"Q30715565","url":"https://www.wikidata.org/entity/Q30715565"}
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13
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