Sakurai reaction
id:
sakurai-reaction-296-2614548
title:
Sakurai reaction
text:
The Sakurai reaction (also known as the Hosomi–Sakurai reaction) is the chemical reaction of carbon electrophiles (such as a ketone shown here) with allyltrimethylsilane catalyzed by strong Lewis acids. The reaction achieves results similar to the addition of an allyl Grignard reagent to the carbonyl. Strong Lewis acids such as titanium tetrachloride, boron trifluoride, tin tetrachloride, and AlCl(Et)2 are all effective in promoting the Hosomi reaction. The reaction involves electrophilic allyl
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wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Sakurai_reaction
date created:
date modified:
2024-03-19T20:59:17Z
main entity:
{"identifier":"Q903031","url":"https://www.wikidata.org/entity/Q903031"}
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fields total:
13
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13