Ray–Dutt twist
id:
ray-dutt-twist-286-2675153
title:
Ray–Dutt twist
text:
The Ray–Dutt twist is a mechanism proposed for the racemization of octahedral complexes containing three bidentate chelate rings. Such complexes typically adopt an octahedral molecular geometry in their ground states, in which case they possess helical chirality. The pathway entails formation of an intermediate of C2v point group symmetry. An alternative pathway that also does not break any metal-ligand bonds is called the Bailar twist. Both of these mechanism product complexes wherein the ligat
brand slug:
wiki
category slug:
encyclopedia
description:
Chemical mechanism for isomerization
original url:
https://en.wikipedia.org/wiki/Ray%E2%80%93Dutt_twist
date created:
date modified:
2023-07-17T10:58:52Z
main entity:
{"identifier":"Q7299427","url":"https://www.wikidata.org/entity/Q7299427"}
image:
fields total:
13
integrity:
14