Manganese-mediated coupling reactions
id:
manganese-mediated-coupling-reactions-293-13932320
title:
Manganese-mediated coupling reactions
text:
Manganese-mediated coupling reactions are radical coupling reactions between enolizable carbonyl compounds and unsaturated compounds initiated by a manganese(III) salt, typically manganese(III) acetate. Copper(II) acetate is sometimes used as a co-oxidant to assist in the oxidation of intermediate radicals to carbocations. Manganese(III) acetate is effective for the one-electron oxidation of enolizable carbonyl compounds to α-oxoalkyl or α,α'-dioxoalkyl radicals. Radicals generated in this manne
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Manganese-mediated_coupling_reactions
date created:
date modified:
2023-09-25T14:03:57Z
main entity:
{"identifier":"Q6748776","url":"https://www.wikidata.org/entity/Q6748776"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/8/86/MnCoupleGen.png","width":411,"height":160}
fields total:
13
integrity:
14