Leimgruber–Batcho indole synthesis

id: leimgruber-batcho-indole-synthesis-170-9913968
title: Leimgruber–Batcho indole synthesis
text: The Leimgruber–Batcho indole synthesis is a series of organic reactions that produce indoles from o-nitrotoluenes 1. The first step is the formation of an enamine 2 using N,N-dimethylformamide dimethyl acetal and pyrrolidine. The desired indole 3 is then formed in a second step by reductive cyclisation. In the above scheme, the reductive cyclisation is effected by Raney nickel and hydrazine. Palladium-on-carbon and hydrogen, stannous chloride, sodium hydrosulfite, or iron in acetic acid are also
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category slug: encyclopedia
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original url: https://en.wikipedia.org/wiki/Leimgruber%E2%80%93Batcho_indole_synthesis
date created: 2005-07-16T19:55:13Z
date modified: 2024-08-31T23:51:33Z
main entity: {"identifier":"Q2390993","url":"https://www.wikidata.org/entity/Q2390993"}
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integrity: 14

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