Krische allylation
id:
krische-allylation-280-17012308
title:
Krische allylation
text:
The Krische allylation involves the enantioselective iridium-catalyzed addition of an allyl group to an aldehyde or an alcohol, resulting in the formation of a secondary homoallylic alcohol. The mechanism of the Krische allylation involves primary alcohol dehydrogenation or, when using aldehyde reactants, hydrogen transfer from 2-propanol. Unlike other allylation methods, the Krische allylation avoids the use of preformed allyl metal reagents and enables the direct conversion of primary alcohols
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Krische_allylation
date created:
date modified:
2022-11-24T19:20:44Z
main entity:
{"identifier":"Q30693024","url":"https://www.wikidata.org/entity/Q30693024"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/b/bc/General_scheme_of_Krische_Allylation.png","width":1025,"height":331}
fields total:
13
integrity:
14