Kharasch–Sosnovsky reaction
id:
kharasch-sosnovsky-reaction-169-11762001
title:
Kharasch–Sosnovsky reaction
text:
The Kharasch–Sosnovsky reaction is a method that involves using a copper or cobalt salt as a catalyst to oxidize olefins at the allylic position, subsequently condensing a peroxy ester or a peroxide resulting in the formation of allylic benzoates or alcohols via radical oxidation. This method is noteworthy for being the first allylic functionalization to utilize first-row transition metals and has found numerous applications in chemical and total synthesis. Chiral ligands can be used to render t
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Kharasch%E2%80%93Sosnovsky_reaction
date created:
2013-05-26T20:05:57Z
date modified:
2024-08-31T23:50:56Z
main entity:
{"identifier":"Q16900433","url":"https://www.wikidata.org/entity/Q16900433"}
image:
fields total:
13
integrity:
14