Ketimine Mannich reaction

id: ketimine-mannich-reaction-275-7156174
title: Ketimine Mannich reaction
text: The ketimine Mannich reaction is an asymmetric synthetic technique using differences in starting material to push a Mannich reaction to create an enantiomeric product with steric and electronic effects, through the creation of a ketimine group. Typically, this is done with a reaction with proline or another nitrogen-containing heterocycle, which control chirality with that of the catalyst. This has been theorized to be caused by the restriction of undesired (E)-isomer by preventing the ketone fr
brand slug: wiki
category slug: encyclopedia
description: Chemical reaction
original url: https://en.wikipedia.org/wiki/Ketimine_Mannich_reaction
date created:
date modified: 2024-02-03T00:21:40Z
main entity: {"identifier":"Q110864182","url":"https://www.wikidata.org/entity/Q110864182"}
image:
fields total: 13
integrity: 14

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