High dilution principle
id:
high-dilution-principle-268-2494846
title:
High dilution principle
text:
In organic chemistry, the high dilution principle is a strategy for some macrocyclization reactions, i.e. the synthesis of macrocycles. Unlike the synthesis of 5- and 6-membered rings, the preparation of larger rings competes unfavorably with polymerization reactions. Polymers arise from coupling of long chain precursors. Such reactions are disfavored when the acyclic compounds are dilute. Although high dilution reactions can be conducted in a batch reactor with large volumes of solvent, an alte
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wiki
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encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/High_dilution_principle
date created:
date modified:
2023-09-24T13:14:37Z
main entity:
{"identifier":"Q60794576","url":"https://www.wikidata.org/entity/Q60794576"}
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13
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