Herz reaction

id: herz-reaction-200-674676
title: Herz reaction
text: The Herz reaction, named after the chemist Richard Herz, is the chemical conversion of an aniline to the benzodithiazolium salt by its reaction with disulfur dichloride. The salt is called a Herz salt. Hydrolysis of this Herz salt give the corresponding sodium thiolate, which can be further converted to the 2-aminothiophenol. The 2-aminothiophenols are suitable for diazotization, giving benzothiadiazoles. Instead the sodium 2-aminothiophenolate can be converted to a 1,3-benzothiazole.
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category slug: encyclopedia
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original url: https://en.wikipedia.org/wiki/Herz_reaction
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date modified: 2023-10-31T14:45:54Z
main entity: {"identifier":"Q2728528","url":"https://www.wikidata.org/entity/Q2728528"}
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