Enantiomer self-disproportionation
id:
enantiomer-self-disproportionation-224-4609435
title:
Enantiomer self-disproportionation
text:
Enantiomer self-disproportionation is a process in stereochemistry describing the separation of a non-racemic mixture of enantiomers in an enantioenriched fraction and a more racemic fraction as a result of the formation of heterochiral or homochiral aggregates. This process is known to occur in achiral column chromatography. The phenomenon was first reported in 1983 in the separation of an excess of
carbon-14 labeled (S)-(−)-nicotine enantiomer and its isomer. Two fractions were recorded, one c
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Enantiomer_self-disproportionation
date created:
2006-02-04T21:23:28Z
date modified:
2024-09-14T16:29:03Z
main entity:
{"identifier":"Q5375225","url":"https://www.wikidata.org/entity/Q5375225"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/d/d6/Enantiomerdisproportionation.png","width":339,"height":215}
fields total:
13
integrity:
15