Doering–LaFlamme allene synthesis
id:
doering-laflamme-allene-synthesis-322-12753515
title:
Doering–LaFlamme allene synthesis
text:
In organic chemistry, the Doering–LaFlamme allene synthesis is a reaction of alkenes that converts them to allenes by insertion of a carbon atom. This name reaction is named for William von Eggers Doering and a co-worker, who first reported it. The reaction is a two-stage process, in which first the alkene is reacted with dichlorocarbene or dibromocarbene to form a dihalocyclopropane. This intermediate is then reacted with a reducing metal, such as sodium or magnesium, or with an organolithium r
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https://en.wikipedia.org/wiki/Doering%E2%80%93LaFlamme_allene_synthesis
date created:
date modified:
2022-04-29T11:10:19Z
main entity:
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