Buchner ring expansion

id: buchner-ring-expansion-186-14617250
title: Buchner ring expansion
text: The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in the second step, with an electrocyclic reaction opening the cyclopropane ring to form the 7-membered ring.
brand slug: wiki
category slug: encyclopedia
description:
original url: https://en.wikipedia.org/wiki/Buchner_ring_expansion
date created: 2011-12-06T18:18:42Z
date modified: 2024-09-08T08:18:46Z
main entity: {"identifier":"Q4982728","url":"https://www.wikidata.org/entity/Q4982728"}
image:
fields total: 13
integrity: 14

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