Bond stretch isomer
id:
bond-stretch-isomer-272-4580329
title:
Bond stretch isomer
text:
In chemistry, bond stretch isomerism is a concept of isomerism based on variations of bond length. The concept was proposed in the 1970s but was refuted in the 1990s. The phenomenon was first invoked to explain the observation of blue and green isomers of mer-MoOCl2(PMe2Ph)3, where PMe2Ph is dimethylphenylphosphine. These isomers were shown, purportedly, by X-ray crystallography to differ with respect to the length of the Mo-O bond, which differed by 0.2 Å. Subsequent work showed that the suppos
brand slug:
wiki
category slug:
encyclopedia
description:
Proposed type of chemical isomerism based on bond length
original url:
https://en.wikipedia.org/wiki/Bond_stretch_isomer
date created:
date modified:
2023-07-16T22:14:04Z
main entity:
{"identifier":"Q28405278","url":"https://www.wikidata.org/entity/Q28405278"}
image:
fields total:
13
integrity:
14