Benzylic activation and stereocontrol in tricarbonyl(arene)chromium complexes
id:
benzylic-activation-and-stereocontrol-in-tricarbonyl-arene-chromium-complexes-266-9810838
title:
Benzylic activation and stereocontrol in tricarbonyl(arene)chromium complexes
text:
Benzylic activation and stereocontrol in tricarbonyl(arene)chromium complexes refers to the enhanced rates and stereoselectivities of reactions at the benzylic position of aromatic rings complexed to chromium(0) relative to uncomplexed arenes. Complexation of an aromatic ring to chromium stabilizes both anions and cations at the benzylic position and provides a steric blocking element for diastereoselective functionalization of the benzylic position. A large number of stereoselective methods for
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Benzylic_activation_and_stereocontrol_in_tricarbonyl(arene)chromium_complexes
date created:
date modified:
2023-09-09T00:01:00Z
main entity:
{"identifier":"Q4890817","url":"https://www.wikidata.org/entity/Q4890817"}
image:
fields total:
13
integrity:
13