Apicophilicity
id:
apicophilicity-306-8024904
title:
Apicophilicity
text:
Apicophilicity is the phenomenon in which electronegative substituents of trigonal bipyramidal pentacoordinate compounds prefer to occupy apical (axial) positions (Lap). The term "apicophilicity" was first proposed by Earl L. Muetterties in 1963 for the structural analysis of pentacoordinate phosphorus fluorides by 19F NMR. Since the apical bonding of a pentacoordinate typical element compound consists of a 3-center-4-electron bond, in which the electron density is localized on two apical substi
brand slug:
wiki
category slug:
encyclopedia
description:
original url:
https://en.wikipedia.org/wiki/Apicophilicity
date created:
date modified:
2022-10-24T12:02:20Z
main entity:
{"identifier":"Q4779825","url":"https://www.wikidata.org/entity/Q4779825"}
image:
{"content_url":"https://upload.wikimedia.org/wikipedia/commons/d/df/Phosphorus-chloride-tetrafluoride-3D-balls.png","width":1062,"height":1100}
fields total:
13
integrity:
14